To name a compound you must first decide whether the substance is an ionic or molecular compound. Ionic compounds are easily recognized since they usually contain both metallic and non-metallic elements. The most common exception to this rule are ionic compounds containing the ammonium ion, NH4+, such as (NH4)2CO3 or NH4Br which contain no metal ions. Molecular compounds typically contain only non-metallic atoms (and metalloids).
Conventions for naming ionic compounds are given in your Text To successfully follow the rules, however, you must be first learn the names of common ions . Names of ionic compounds do not give the number of each type of ion in the formula: the chemist is supposed to be able to figure that out from his/her knowledge of ion charges and the requirement that salts be neutral (and thus have a sum of zero for the ion charges in the formula).
Binary compounds of the non-metals are named following the guidelines given in your Text. Note that when naming these molecular compounds, the number of atoms of a given type is commonly indicated with a prefix (di-, tri-, tetra, etc.).
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Exercises
1. Complete the following chart of corresponding ion names and formulas.
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| (1) potassium ion | (11) nitrate ion | |||
| (2) |
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(12) |
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| (3) ammonium ion | (13) hydrogen carbonate (or bicarbonate) ion | |||
| (4) |
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(14) |
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| (5) silver ion | (15) perchlorate ion | |||
| (6) |
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(16) |
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| (7) zinc ion | (17) acetate ion | |||
| (8) |
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(18) dichromate ion | ||
| (9) hydrogen ion | (19) |
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| (10) chromium(III) ion | (20) sulfite ion |
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| (1) silver nitrate | (11) sodium hydrogen phosphate | |||
| (2) |
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(12) |
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| (3) ammonium sulfate | (13) potassium permanganate | |||
| (4) |
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(14) |
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| (5) sodium oxide | (15) cobalt(III) sulfate | |||
| (6) |
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(16) |
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| (7) nitrogen trichloride | (17) |
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| (8) |
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(18) sulfur hexafluoride | ||
| (9) iron(II) acetate | (19) |
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| (10) carbon tetrachloride | (20) |
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